Five decades of homonuclear dipolar decoupling in solid-state NMR: Status and outlook

Kaustubh R Mote; Vipin Agarwal; P K Madhu

doi:10.1016/j.pnmrs.2016.08.001

Five decades of homonuclear dipolar decoupling in solid-state NMR: Status and outlook

Prog Nucl Magn Reson Spectrosc. 2016 Nov:97:1-39. doi: 10.1016/j.pnmrs.2016.08.001. Epub 2016 Aug 4.

Authors

Kaustubh R Mote¹, Vipin Agarwal¹, P K Madhu²

Affiliations

¹ TIFR Centre for Interdisciplinary Sciences, Tata Institute of Fundamental Research, 21 Brundavan Colony, Narsingi, Hyderabad 500 075, India.
² TIFR Centre for Interdisciplinary Sciences, Tata Institute of Fundamental Research, 21 Brundavan Colony, Narsingi, Hyderabad 500 075, India; Department of Chemical Sciences, Tata Institute of Fundamental Research, Homi Bhabha Road, Colaba, Mumbai 400 005, India.

PMID: 27888838
DOI: 10.1016/j.pnmrs.2016.08.001

Abstract

It has been slightly more than fifty years since the first homonuclear spin decoupling scheme, Lee-Goldburg decoupling, was proposed for removing homonuclear dipolar interactions in solid-state nuclear magnetic resonance. A family of such schemes has made observation of high-resolution NMR spectra of abundant spins possible in various applications in solid state. This review outlines the strategies used in this field and the future prospects of homonuclear spin decoupling in solid-state NMR.

Keywords: resolution; DUMBO; Homonuclear decoupling; Lee-Goldburg; Magic-angle spinning; PMLG; Solid-state NMR.

Publication types

Review