Rapid and wide-range determination of Cd(II), Pb(II), Cu(II) and Hg(II) in fish tissues using light addressable potentiometric sensor

Food Chem. 2017 Apr 15:221:541-547. doi: 10.1016/j.foodchem.2016.11.141. Epub 2016 Nov 28.

Abstract

A rapid and wide-range method, based on light addressable potentiometric sensor (LAPS), is introduced into determination of Cd(II), Pb(II), Cu(II) and Hg(II) in fish tissues. A compact LAPS module is prepared by integrating four LAPS chips specifically sensitive to target elements. Its responses in digestions from various settings are investigated to find suitable factors. Analytical properties of this method are evaluated in consequent experiments under optimized conditions. Measurement range for each target element exceeds 0.1 to 1000mgL-1, and response time is less than 10s. Accuracy, precision and selectivity of the proposed method are also well defined in measurements. It is successively performed to detect the target elements in real fish samples from 4 species, and obtained results are consistent with certified method.

Keywords: Light addressable potentiometric sensor; Specific sensing; Wide-range determination.

MeSH terms

  • Animals
  • Biosensing Techniques / methods*
  • Cadmium / analysis*
  • Cadmium / metabolism
  • Copper / analysis*
  • Copper / metabolism
  • Fishes / metabolism
  • Lead / analysis*
  • Lead / metabolism
  • Light
  • Mercury / analysis*
  • Mercury / metabolism
  • Potentiometry / methods*
  • Time Factors
  • Tissue Distribution / physiology

Substances

  • Cadmium
  • Lead
  • Copper
  • Mercury