Unusual binding selectivity with non-selective homoditopic pillar[5]arene oxime: serendipitous discovery of a unique approach to heterobinuclear metalation in solution

Xiangyang Yuan; Yiming Jia; Yimin Cai; Wen Feng; Yiming Li; Xiaopeng Li; Lihua Yuan

doi:10.1039/c7cc00237h

Unusual binding selectivity with non-selective homoditopic pillar[5]arene oxime: serendipitous discovery of a unique approach to heterobinuclear metalation in solution

Chem Commun (Camb). 2017 Mar 2;53(19):2838-2841. doi: 10.1039/c7cc00237h.

Authors

Xiangyang Yuan¹, Yiming Jia¹, Yimin Cai¹, Wen Feng¹, Yiming Li², Xiaopeng Li², Lihua Yuan¹

Affiliations

¹ Institute of Nuclear Science and Technology, Key Laboratory for Radiation Physics and Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China. [email protected] [email protected].
² Department of Chemistry, University of South Florida, East Fowler Ave, Florida 4202, USA. [email protected].

PMID: 28217779
DOI: 10.1039/c7cc00237h

Abstract

A heterobinuclear complexation strategy on homoditopic pillar[5]arene was developed by using a pillar[5]arene with two rims decorated with benzaldehyde oximes. The unique selective recognition process was found to result from vesicular formation based on a controllable self-assembly, leading to binding of thorium(iv) only onto one rim, with the other rim being unoccupied for subsequent complexation of a second different metal ion.