Stability of Polar Vortex Lattice in Ferroelectric Superlattices

Nano Lett. 2017 Apr 12;17(4):2246-2252. doi: 10.1021/acs.nanolett.6b04875. Epub 2017 Mar 8.

Abstract

A novel mesoscale state comprising of an ordered polar vortex lattice has been demonstrated in ferroelectric superlattices of PbTiO3/SrTiO3. Here, we employ phase-field simulations, analytical theory, and experimental observations to evaluate thermodynamic conditions and geometric length scales that are critical for the formation of such exotic vortex states. We show that the stability of these vortex lattices involves an intimate competition between long-range electrostatic, long-range elastic, and short-range polarization gradient-related interactions leading to both an upper and a lower bound to the length scale at which these states can be observed. We found that the critical length is related to the intrinsic domain wall width, which could serve as a simple intuitive design rule for the discovery of novel ultrafine topological structures in ferroic systems.

Keywords: Ferroelectric superlattices; geometric length scale; phase-field simulations; topological structures by design; ultrafine polar vortex.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.