New LC-MS/MS Method for the Analysis of Allura Red Level in Takeaway Chinese Dishes and Urine of an Adult Chinese Population

J Agric Food Chem. 2017 Mar 29;65(12):2588-2593. doi: 10.1021/acs.jafc.6b05310. Epub 2017 Mar 15.

Abstract

Allura red is a widely used synthetic food dye. In this study, we developed and validated a LC-MS/MS method for the quantification of allura red in three popular takeaway Chinese dishes (braised pork, soy sauce chicken, sweet and sour pork) and human urine samples. High levels of allura red ranging from 2.85 to 8.38 mg/g wet weight were detected in the surveyed Chinese dishes. Of 113 participants who frequently consume the surveyed Chinese dishes (>once a week in the past 2 years), the median of their urinary allura red level was 22.29 nM/mM creatinine (95% CI = 19.48-25.03) . Risk assessment using Cox proportional hazard models showed that a 10-fold increase in urinary allura red was positively associated with high blood pressure (odds ratio of 1.75 (95% CI = 0.78-3.96)). Our findings provide new insights for the potential risk of hypertension for long-term allura red overconsumption.

Keywords: Chinese dishes; LC-MS/MS; allura red; high blood pressure; long-term exposure; urine.

Publication types

  • Evaluation Study

MeSH terms

  • Adult
  • Animals
  • Azo Compounds / urine*
  • Chickens
  • Chromatography, High Pressure Liquid / methods*
  • Female
  • Food Coloring Agents / analysis*
  • Humans
  • Limit of Detection
  • Male
  • Meat Products / analysis*
  • Swine
  • Tandem Mass Spectrometry / methods*
  • Young Adult

Substances

  • Azo Compounds
  • Food Coloring Agents
  • Allura Red AC Dye