We investigate how population mixing leads to structured electron distribution functions in asymmetric guide-field magnetic reconnection based on particle-in-cell simulations. The change of magnetic connectivity patches populations from different inflow regions to form multicomponent distributions in the exhaust, illustrating the direct consequence of the breaking and rejoining of magnetic flux tubes. Finite Larmor radius (FLR) effects of electrons accelerated by the perpendicular electric fields result in crescent-type nongyrotropic distributions. A new type of nongyrotropy is found to be caused by the combined effects of the FLR and velocity dispersion of electrons accelerated by the parallel electric field. The patching together of populations and the effects of acceleration and the FLR form the first steps of mixing in the exhaust and separatrix regions.