Selected cholesterol biosynthesis inhibitors produce accumulation of the intermediate FF-MAS that targets nucleus and activates LXRα in HepG2 cells

Biochim Biophys Acta Mol Cell Biol Lipids. 2017 Sep;1862(9):842-852. doi: 10.1016/j.bbalip.2017.05.004. Epub 2017 May 9.

Abstract

Sterol intermediates of the cholesterol biosynthetic pathway have drawn attention for novel biological activities. Follicular fluid meiosis activating sterol (FF-MAS) is a LXRα ligand and a potential modulator of physiologic processes regulated by nuclear receptors, such as lipid homeostasis and cell proliferation. In this work, we established a model to selectively accumulate FF-MAS in HepG2 cells, by using a combination of the inhibitors AY9944 and 17-hydroxyprogesterone to block C14-sterol reductases and the downstream C4-demethylase complex. We investigated the effects produced by altered levels of cholesterol biosynthesis intermediates, in order to dissect their influence on LXRα signaling. In particular, endogenously accumulated FF-MAS was able to modulate the expression of key genes in cholesterol metabolism, to activate LXRα nuclear signaling resulting in increased lipogenesis, and to inhibit HepG2 cells proliferation. Moreover, a fluorescent ester derivative of FF-MAS localized in nuclear lipid droplets, suggesting a role for these organelles in the storage of signaling lipids interacting with nuclear partners.

Keywords: Cholesterol biosynthesis inhibitors; FF-MAS; LXRα; Nuclear lipid droplets.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • 17-alpha-Hydroxyprogesterone / pharmacology*
  • Cell Line
  • Cell Line, Tumor
  • Cell Nucleus / drug effects*
  • Cell Nucleus / metabolism*
  • Cell Proliferation / drug effects
  • Cholestenes / metabolism*
  • Cholesterol / metabolism*
  • HEK293 Cells
  • HeLa Cells
  • Hep G2 Cells
  • Humans
  • Lipid Droplets / drug effects
  • Lipid Droplets / metabolism
  • Lipids / chemistry
  • Liver X Receptors / metabolism*
  • Receptors, Cytoplasmic and Nuclear / metabolism
  • Signal Transduction / drug effects
  • trans-1,4-Bis(2-chlorobenzaminomethyl)cyclohexane Dihydrochloride / pharmacology*

Substances

  • Cholestenes
  • Lipids
  • Liver X Receptors
  • Receptors, Cytoplasmic and Nuclear
  • trans-1,4-Bis(2-chlorobenzaminomethyl)cyclohexane Dihydrochloride
  • 4,4-dimethylcholesta-8,14,24-trienol
  • 17-alpha-Hydroxyprogesterone
  • Cholesterol