Lipid profiling of complex biological mixtures by liquid chromatography/mass spectrometry using a novel scanning quadrupole data-independent acquisition strategy

Rapid Commun Mass Spectrom. 2017 Oct 15;31(19):1599-1606. doi: 10.1002/rcm.7941.

Abstract

Rationale: A novel data-independent acquisition method is detailed that incorporates a scanning quadrupole in front of an orthogonal acceleration time-of-flight (TOF) mass analyser. This approach is described and the attributes are compared and contrasted to other DIA approaches.

Methods: Specific application of the method to both targeted and untargeted lipidomic identification strategies is discussed, with data from both shotgun and LC separated lipidomics experiments presented.

Results: The benefits of the fast quadrupole scanning technique are highlighted, and include improvements in speed and specificity for complex mixtures providing high quality qualitative and quantitative data.

Conclusions: In particular the high specificity afforded by the scanning quadrupole improves qualitative information for lipid identification.

MeSH terms

  • Animals
  • Cattle
  • Chromatography, High Pressure Liquid / methods*
  • Lipids / analysis*
  • Male
  • Mass Spectrometry / methods*
  • Metabolomics / methods
  • Mice
  • Myocardium / chemistry
  • Testis / chemistry

Substances

  • Lipids