Solubilization of α-galactosylceramide in aqueous medium: Impact on Natural Killer T cell activation and antitumor responses

Int J Pharm. 2017 Sep 15;530(1-2):354-363. doi: 10.1016/j.ijpharm.2017.07.054. Epub 2017 Jul 22.

Abstract

The potent antitumor effect of α-galactosylceramide (α-GalCer) is based on its recognition by invariant Natural Killer T cells (iNKT) after its capture and presentation by antigen presenting cells including dendritic cells (DCs). Synthetic α-GalCer has already been tested in advanced cancer patients but no or only moderate clinical responses were obtained. To optimize α-GalCer efficacy, we have postulated that alternative formulations impacting its molecular organization in aqueous medium could modify DC uptake and iNKT-based immune responses. To this end, we have developed two strategies: (1) the formulation of α-GalCer in non-cationic liposomes and (2) the synthesis of a water-soluble α-GalCer analogue by anchoring a polyethyleneglycol moiety on its sugar head. The biological activities of these new preparations were compared to that induced by the classically used Polysorbate 20 α-GalCer micelles. Both formulations retained their uptake by DCs and activated iNKT cells both in vitro and in vivo. Despite a lower cytokine production, the formulations induced a potent immune response able to control lung murine carcinoma. In conclusion, it is possible to increase α-GalCer solubility in aqueous solution without limiting its antitumor properties.

Keywords: Cancer; Liposomes; Micelles; Water-soluble α-GalCer; iNKT; α-GalCer formulations.

MeSH terms

  • Animals
  • Antineoplastic Agents / chemistry*
  • Cell Line, Tumor
  • Drug Carriers / chemistry
  • Galactosylceramides / chemistry*
  • Liposomes / chemistry
  • Lung Neoplasms / drug therapy*
  • Lung Neoplasms / immunology
  • Lymphocyte Activation / drug effects*
  • Male
  • Mice
  • Mice, Inbred C57BL
  • Natural Killer T-Cells / drug effects*

Substances

  • Antineoplastic Agents
  • Drug Carriers
  • Galactosylceramides
  • Liposomes
  • alpha-galactosylceramide