A mild post-functionalization method for the vanadium substituted P2W15V3 Wells-Dawson polyoxometalate based on a copper catalyzed azide-alkyne cycloaddition

S Vanhaecht; T Quanten; T N Parac-Vogt

doi:10.1039/c7dt02450a

A mild post-functionalization method for the vanadium substituted P₂W₁₅V₃ Wells-Dawson polyoxometalate based on a copper catalyzed azide-alkyne cycloaddition

Dalton Trans. 2017 Aug 8;46(31):10215-10219. doi: 10.1039/c7dt02450a.

Authors

S Vanhaecht¹, T Quanten, T N Parac-Vogt

Affiliation

¹ Department of Chemistry, KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium. [email protected].

PMID: 28749501
DOI: 10.1039/c7dt02450a

Abstract

A mild post-functionalization method, based on a copper(i) catalyzed azide-alkyne cycloaddition, was developed for the fragile [P₂W₁₅V₃]^9- (PWV). PWV was functionalized with an azide and used as a platform to attach various alkyne functionalized compounds.