Infrared-Assisted Extraction and HPLC-Analysis of Prunus armeniaca L. Pomace and Detoxified-Kernel and their Antidiabetic Effects

Phytochem Anal. 2018 Mar;29(2):156-167. doi: 10.1002/pca.2723. Epub 2017 Sep 12.

Abstract

Introduction: Prunus armeniaca L. (P. armeniaca) is one of the medicinal plants with a high safety-profile.

Objectives: The aim of this work was to make an infrared-assisted extraction (IR-AE) of P. armeniaca fruit (pomace) and kernel, and analyse them using reverse phase high-performance liquid chromatography (RP-HPLC) aided method.

Methods: IR-AE is a novel-technique aimed at increasing the extraction-efficiency. The antidiabetic-potentials of the P. armeniaca pomace (AP) and the detoxified P. armeniaca kernel extract (DKAP) were monitored exploring their possible hypoglycemic-mechanisms. Acute (6 h), subchronic (8 days) and long-term (8 weeks) assessment of Diabetes mellitus (DM) using glucometers and glycated hemoglobin (HbA1c) methods were applied.

Results: Serum-insulin levels, the inhibitory effects on alpha-glucosidase, serum-catalase (CAT) and lipid peroxidation (LPO) levels were also monitored. AP was shown to be rich in polyphenolics like trans-lutein (14.1%), trans-zeaxanthin (10.5%), trans-ß-cryptoxanthin (11.6%), 13, cis-ß-carotene (6.5%), trans 9, cis-ß-carotene (18.4%), and ß-carotene (21.5%). Prunus armeniaca kernel extract before detoxification (KAP) was found to be rich in amygdaline (16.1%), which caused a high mortality rate (50.1%), while after detoxification (amygdaline, 1.4%) a lower mortality rate (9.1%) was found. AP showed significant (p ≤ 0.05, n = 7/group) antidiabetic-activity more prominent than DKAP acutely, subchronically and on longer-terms. IR-AEs displayed more efficient acute and subchronic blood glucose level (BGL) reduction than a conventional extraction method, which might be attributed to IR-AE superiority in extraction of active ingredients. AP showed more-significant and dose-dependent increase in serum-insulin, CAT-levels and body-weights more prominent than those of DKAP. Alpha-glucosidase and LPO levels were inhibited with AP-groups more-significantly.

Conclusion: In comparison to conventional-methods, IR-AE appeared to be an efficient and time-conserving novel extraction method. The antidiabetic-potentials of pomace and detoxified-kernels of P. armeniaca were probably mediated via the attenuation of glucose-provoked oxidative-stress, the inhibition of alpha-glucosidase and the marked insulin-secretagogue effect. Copyright © 2017 John Wiley & Sons, Ltd.

Keywords: Diabetes mellitus; P. armeniaca; RP-HPLC; infrared-assisted extraction; kernel detoxification.

MeSH terms

  • Alloxan
  • Animals
  • Catalase / blood
  • Chromatography, High Pressure Liquid / methods*
  • Chromatography, Reverse-Phase / methods*
  • Diabetes Mellitus, Experimental / blood
  • Diabetes Mellitus, Experimental / drug therapy*
  • Dose-Response Relationship, Drug
  • Glycated Hemoglobin / metabolism
  • Hypoglycemic Agents / adverse effects
  • Hypoglycemic Agents / chemistry
  • Hypoglycemic Agents / isolation & purification*
  • Hypoglycemic Agents / therapeutic use
  • Infrared Rays*
  • Insulin / blood
  • Lipid Peroxidation / drug effects
  • Male
  • Mice
  • Plant Extracts / adverse effects
  • Plant Extracts / chemistry
  • Plant Extracts / isolation & purification*
  • Plant Extracts / therapeutic use
  • Plants, Medicinal / chemistry
  • Polyphenols / analysis
  • Prunus / chemistry*
  • Prunus / embryology
  • Seeds / chemistry*
  • alpha-Glucosidases / blood

Substances

  • Glycated Hemoglobin A
  • Hypoglycemic Agents
  • Insulin
  • Plant Extracts
  • Polyphenols
  • Alloxan
  • Catalase
  • alpha-Glucosidases