Synthesis and catalytic application of magnetic Co-Cu nanowires

Beilstein J Nanotechnol. 2017 Aug 25:8:1769-1773. doi: 10.3762/bjnano.8.178. eCollection 2017.

Abstract

A rapid, template-free method was developed to prepare magnetic, bimetallic Co-Cu nanowires via liquid phase reduction and metal replacement under an external magnetic field. The characterization results confirmed that the as-prepared product was bimetallic Co-Cu nanowires with a desirable linear structure. Additionally, the magnetic hysteresis loop showed that the bimetallic Co-Cu nanowires were paramagnetic, which meant they could be easily separated from the reaction mixture. Furthermore, they were applied to the hydrolysis system of ammonia borane as a catalyst for the first time. More importantly, the catalysis results showed that the bimetallic nanowires possessed appealing catalytic performance. Therefore, a rapid and facile synthesis method is introduced which is capable of preparing bimetallic Co-Cu nanowires with great potential for industrial applications.

Keywords: Co–Cu nanowires; catalyst; liquid phase reduction; magnetic materials; metal replacement.