Molecular determinants of PPARγ partial agonism and related in silico/in vivo studies of natural saponins as potential type 2 diabetes modulators

Food Chem Toxicol. 2018 Feb:112:47-59. doi: 10.1016/j.fct.2017.12.009. Epub 2017 Dec 13.

Abstract

The metabolic syndrome, which includes hypertension, type 2 diabetes (T2D) and obesity, has reached an epidemic-like scale. Saponins and sapogenins are considered as valuable natural products for ameliorating this pathology, possibly through the nuclear receptor PPARγ activation. The aims of this study were: to look for in vivo antidiabetic effects of a purified saponins' mixture (PSM) from Astragalus corniculatus Bieb; to reveal by in silico methods the molecular determinants of PPARγ partial agonism, and to investigate the potential PPARγ participation in the PSM effects. In the in vivo experiments spontaneously hypertensive rats (SHRs) with induced T2D were treated with PSM or pioglitazone as a referent PPARγ full agonist, and pathology-relevant biochemical markers were analysed. The results provided details on the PSM modulation of the glucose homeostasis and its potential mechanism. The in silico studies focused on analysis of the protein-ligand interactions in crystal structures of human PPARγ-partial agonist complexes, pharmacophore modelling and molecular docking. They outlined key pharmacophoric features, typical for the PPARγ partial agonists, which were used for pharmacophore-based docking of the main PSM sapogenin. The in silico studies, strongly suggest possible involvement of PPARγ-mediated mechanisms in the in vivo antidiabetic and antioxidant effects of PSM from A. corniculatus.

Keywords: Docking; PPARγ; Partial agonists; Pharmacophore; Saponins; Type 2 diabetes.

MeSH terms

  • Animals
  • Antioxidants / therapeutic use*
  • Biomarkers / metabolism
  • Blood Glucose / metabolism
  • Catalase / metabolism
  • Computer Simulation
  • Diabetes Mellitus, Type 2 / blood
  • Diabetes Mellitus, Type 2 / drug therapy*
  • Disease Models, Animal
  • Drug Partial Agonism*
  • Homeostasis
  • Humans
  • Hypoglycemic Agents / therapeutic use*
  • Male
  • Molecular Docking Simulation
  • Oxidative Stress
  • PPAR gamma / agonists*
  • Pioglitazone
  • Rats, Inbred SHR
  • Saponins / therapeutic use*
  • Superoxide Dismutase / metabolism
  • Thiazolidinediones / therapeutic use

Substances

  • Antioxidants
  • Biomarkers
  • Blood Glucose
  • Hypoglycemic Agents
  • PPAR gamma
  • Saponins
  • Thiazolidinediones
  • Catalase
  • Superoxide Dismutase
  • Pioglitazone