Preparation of a Smart and Portable Film for in Situ Sensing of Iron Microcorrosion

Corrosion of iron-containing materials, which presents serious economic and safety problems, normally begins with microcorrosion, which refers to the early stages of corrosion before visible changes appear on the surface. If microcorrosion could be detected and repaired immediately, corrosion damage could be greatly reduced. Current technology and materials, however, are not able to detect microcorrosion of iron in a cheap and convenient manner. Here, we have used a natural product, ellagic acid (EA), to fabricate an EA-functionalized poly(vinyl alcohol) (PVA) film (EAF) for in situ sensing of the initial stage of microcorrosion. EAF was able to effectively sense iron microcorrosion via an obvious color change. The film also had good long-term stability and mechanical strength. Since EAF can be easily prepared from inexpensive and green raw materials, the film opens up a new opportunity for the detection of iron microcorrosion.