Characterization study and optimization of swelling behavior for p(HEMA-co-Eudragit L-100) hydrogels by using Taguchi Method

Biomed Mater Eng. 2018;29(2):191-203. doi: 10.3233/BME-171722.

Abstract

The aim of this study is to produce the smart hydrogel to use insulin release for human body. p(HEMA-co-Eudragit L-100) hydrogels containing different ratios of 2-Hydroxyethyl methacrylate (HEMA) and Eudragait L-100 were synthesized by using ammonium persulfate (APS) as an initiator and ethylene glycol dimethacrylate (EGDMA) as a cross linker. The structures of hydrogels produced were characterized by using Fourier Transform Infrared Spectroscopy (FT-IR) and Scanning electron microscope (SEM) analysis. In this way, optimum synthesis conditions were determined for p(HEMA-co-Eudragit L-100) hydrogels by using Taguchi method as an optimization method. The gelling percentages of all hydrogels were calculated. After all, the swelling behaviors (%) of hydrogels were investigated in range of various times (1-44 hrs), temperatures (20-50°C) and pH (2-12) and the optimum process conditions in the production of hydrogels were determined. Consequently, the optimum time, temperature and pH were 24 hours, 37°C and 7, respectively. Thus, this hydrogel could be evaluated in insulin release for diabetes treatment and drug industry.

Keywords: Hydrogel; optimization; spectroscopy; structure.

MeSH terms

  • Cross-Linking Reagents / chemistry
  • Delayed-Action Preparations / chemistry*
  • Humans
  • Hydrogels / chemistry*
  • Hydrogen-Ion Concentration
  • Hypoglycemic Agents / administration & dosage*
  • Insulin / administration & dosage*
  • Methacrylates / chemistry*
  • Polymethacrylic Acids / chemistry*
  • Spectroscopy, Fourier Transform Infrared
  • Temperature
  • Water / chemistry

Substances

  • Cross-Linking Reagents
  • Delayed-Action Preparations
  • Hydrogels
  • Hypoglycemic Agents
  • Insulin
  • Methacrylates
  • Polymethacrylic Acids
  • Water
  • methylmethacrylate-methacrylic acid copolymer
  • hydroxyethyl methacrylate
  • ethylene dimethacrylate