Total Synthesis of Adunctin B

J Org Chem. 2018 Mar 16;83(6):3392-3396. doi: 10.1021/acs.joc.8b00015. Epub 2018 Feb 23.

Abstract

Total synthesis of (±)-adunctin B, a natural product isolated from Piper aduncum (Piperaceae), has been achieved using two different strategies, in seven and three steps. The efficient approach features highly atom economical and diastereoselective Friedel-Crafts acylation, alkylation reaction and palladium catalyzed Wacker type oxidative cyclization.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkylation
  • Benzofurans / chemical synthesis*
  • Benzofurans / chemistry
  • Chemistry Techniques, Synthetic

Substances

  • Benzofurans