FeS₂ /CoS₂ Interface Nanosheets as Efficient Bifunctional Electrocatalyst for Overall Water Splitting

Electrochemical water splitting to produce hydrogen and oxygen, as an important reaction for renewable energy storage, needs highly efficient and stable catalysts. Herein, FeS₂ /CoS₂ interface nanosheets (NSs) as efficient bifunctional electrocatalysts for overall water splitting are reported. The thickness and interface disordered structure with rich defects of FeS₂ /CoS₂ NSs are confirmed by atomic force microscopy and high-resolution transmission electron microscopy. Furthermore, extended X-ray absorption fine structure spectroscopy clarifies that FeS₂ /CoS₂ NSs with sulfur vacancies, which can further increase electrocatalytic performance. Benefiting from the interface nanosheets' structure with abundant defects, the FeS₂ /CoS₂ NSs show remarkable hydrogen evolution reaction (HER) performance with a low overpotential of 78.2 mV at 10 mA cm^-2 and a superior stability for 80 h in 1.0 m KOH, and an overpotential of 302 mV at 100 mA cm^-2 for the oxygen evolution reaction (OER). More importantly, the FeS₂ /CoS₂ NSs display excellent performance for overall water splitting with a voltage of 1.47 V to achieve current density of 10 mA cm^-2 and maintain the activity for at least 21 h. The present work highlights the importance of engineering interface nanosheets with rich defects based on transition metal dichalcogenides for boosting the HER and OER performance.