A lysine in the ATP-binding site of P130gag-fps is essential for protein-tyrosine kinase activity

EMBO J. 1986 Jan;5(1):69-76. doi: 10.1002/j.1460-2075.1986.tb04179.x.

Abstract

The P130gag-fps transforming protein of Fujinami sarcoma virus (FSV) possesses tyrosine-specific protein kinase activity and autophosphorylates at Tyr-1073. Within the kinase domain of P130gag-fps is a putative ATP-binding site containing a lysine (Lys-950) homologous to lysine residues in cAMP-dependent protein kinase and p60v-src which bind the ATP analogue p-fluorosulfonylbenzoyl-5' adenosine. FSV mutants in which the codon for Lys-950 has been changed to codons for arginine or glycine encode metabolically stable but enzymatically defective proteins which are unable to effect neoplastic transformation. Kinase-defective P130gag-fps containing arginine at residue 950 was normally phosphorylated at serine residues in vivo suggesting that this amino acid substitution has a minimal effect on protein folding and processing. The inability of arginine to substitute for lysine at residue 950 suggests that the side chain of Lys-950 is essential for P130gag-fps catalytic activity, probably by virtue of a specific interaction with ATP at the phosphotransfer active site. Tyr-1073 of the Arg-950 P130gag-fps mutant protein was not significantly autophosphorylated either in vitro or in vivo, but could be phosphorylated in trans by enzymatically active P140gag-fps. These data indicate that Tyr-1073 can be modified by intermolecular autophosphorylation.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adenosine Triphosphate / metabolism
  • Animals
  • Avian Sarcoma Viruses / enzymology
  • Avian Sarcoma Viruses / genetics*
  • Cell Transformation, Neoplastic
  • Codon
  • Gene Products, gag
  • Genes, Viral*
  • Humans
  • Lysine*
  • Mutation
  • Oncogenes*
  • Peptide Fragments / analysis
  • Phosphopeptides / analysis
  • Phosphorylation
  • Protein Binding
  • Protein-Tyrosine Kinases / genetics*
  • Retroviridae Proteins / genetics*
  • Retroviridae Proteins / metabolism
  • Species Specificity

Substances

  • Codon
  • Gene Products, gag
  • Peptide Fragments
  • Phosphopeptides
  • Retroviridae Proteins
  • Adenosine Triphosphate
  • Protein-Tyrosine Kinases
  • Lysine