Colon-targeted dexamethasone microcrystals with pH-sensitive chitosan/alginate/Eudragit S multilayers for the treatment of inflammatory bowel disease

Carbohydr Polym. 2018 Oct 15:198:434-442. doi: 10.1016/j.carbpol.2018.06.107. Epub 2018 Jun 26.

Abstract

Oral colon-targeted drug delivery has gained popularity as an effective strategy for treatment of inflammatory bowel disease (IBD). In this study, we prepared colon-targeted dexamethasone microcrystals (DXMCs) coated with multilayers of chitosan oligosaccharide (CH), alginate (AG), and finally Eudragit S 100 (ES) (ES1AG4CH5-DXMCs) using a layer-by-layer (LBL) coating technique. Particle size, surface charge, in vitro drug release, and in vivo anti-inflammatory activity of ES1AG4CH5-DXMCs were evaluated. ES1AG4CH5-DXMCs had an average particle size of 2.34 ± 0.19 μm and a negative surface charge of - 48 ± 9 mV. ES1AG4CH5-DXMCs demonstrated pH-dependent dexamethasone release, avoiding initial burst drug release in acidic pH conditions of the stomach and small intestine, and providing subsequent sustained drug release in the colonic pH. Importantly, ES1AG4CH5-DXMCs exhibited a significant therapeutic activity in a mouse model of colitis compared to other DXMCs. Overall, the LBL-coated DXMCs presented here could be a promising colon-targeted therapy for IBD.

Keywords: Colon-targeted drug delivery; Dexamethasone; Inflammatory bowel disease; Layer-by-layer coating; Microcrystals.

MeSH terms

  • Alginates / administration & dosage*
  • Alginates / chemistry
  • Animals
  • Anti-Inflammatory Agents / administration & dosage*
  • Anti-Inflammatory Agents / chemistry
  • Chitosan / administration & dosage*
  • Chitosan / chemistry
  • Colitis / chemically induced
  • Colitis / drug therapy*
  • Colitis / metabolism
  • Colitis / pathology
  • Colon / drug effects
  • Colon / metabolism
  • Colon / pathology
  • Cytokines / metabolism
  • Dexamethasone / administration & dosage*
  • Dexamethasone / chemistry
  • Dextran Sulfate
  • Drug Delivery Systems*
  • Drug Liberation
  • Glucuronic Acid / administration & dosage
  • Glucuronic Acid / chemistry
  • Hexuronic Acids / administration & dosage
  • Hexuronic Acids / chemistry
  • Hydrogen-Ion Concentration
  • Male
  • Mice, Inbred ICR
  • Peroxidase / metabolism
  • Polymethacrylic Acids / administration & dosage*
  • Polymethacrylic Acids / chemistry

Substances

  • Alginates
  • Anti-Inflammatory Agents
  • Cytokines
  • Hexuronic Acids
  • Polymethacrylic Acids
  • methylmethacrylate-methacrylic acid copolymer
  • Dexamethasone
  • Glucuronic Acid
  • Chitosan
  • Dextran Sulfate
  • Peroxidase