A Fluorescent Carbon Nanotube Sensor Detects the Metastatic Prostate Cancer Biomarker uPA

ACS Sens. 2018 Sep 28;3(9):1838-1845. doi: 10.1021/acssensors.8b00631. Epub 2018 Aug 31.

Abstract

Therapeutic outcomes in patients with prostate cancer are hindered by the inability to discern indolent versus aggressive disease. To address this problem, we developed a quantitative fluorescent nanosensor for the cancer biomarker urokinase plasminogen activator (uPA). We used the unique fluorescent characteristics of single-walled carbon nanotubes (SWCNT) to engineer an optical sensor that responds to uPA via optical bandgap modulation in complex protein environments. The sensing characteristics of this construct were modulated by passivation of the hydrophobic SWCNT surface with bovine serum albumin (BSA). The sensor enabled quantitative detection of known uPA concentrations in human blood products. These experiments potentiate future use of this technology as a rapid, point-of-care sensor for biomarker measurements in patient fluid samples. We expect that further work will develop a method to discern aggressive vs indolent prostate cancer and reduce overtreatment of this disease.

Keywords: biosensor; nanocarbon; nanomedicine; optical sensor; prostatic carcinoma; protein.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Animals
  • Biomarkers, Tumor / blood*
  • Cattle
  • Fluorescence
  • Fluorescent Dyes / chemistry*
  • Humans
  • Limit of Detection
  • Male
  • Nanotubes, Carbon / chemistry*
  • Point-of-Care Testing
  • Prostatic Neoplasms / diagnosis
  • Serum Albumin, Bovine / chemistry
  • Spectrometry, Fluorescence / methods
  • Urokinase-Type Plasminogen Activator / blood*

Substances

  • Biomarkers, Tumor
  • Fluorescent Dyes
  • Nanotubes, Carbon
  • Serum Albumin, Bovine
  • Urokinase-Type Plasminogen Activator