Antibody-Drug Conjugates with Pyrrole-Based KSP Inhibitors as the Payload Class

Angew Chem Int Ed Engl. 2018 Nov 12;57(46):15243-15247. doi: 10.1002/anie.201807619. Epub 2018 Oct 15.

Abstract

The number of cytotoxic payload classes successfully employed in antibody-drug conjugates (ADCs) is still rather limited. The identification of ADC payloads with a novel mode of action will increase therapeutic options and potentially increase the therapeutic window. Herein, we describe the utilization of kinesin spindle protein inhibitors (KSPi) as a novel payload class providing highly potent ADCs against different targets, for instance HER-2 or TWEAKR/Fn14. Aspects of technical optimization include the development of different linker attachment sites, the stabilization of ADC linkage to avoid payload deconjugation and finally, the tailor-made design of active metabolites with a long lasting intracellular exposure in the tumor matching the mode of action of KSP inhibition. These KSPi-ADCs are highly potent and selective in vitro and demonstrate in vivo efficacy in a broad panel of tumor models including complete regressions in a patient-derived urothelial cancer model.

Keywords: ADC; bioconjugate; cancer; cytotoxicity; drug discovery.

MeSH terms

  • Antineoplastic Agents / chemistry*
  • Antineoplastic Agents / pharmacology*
  • Antineoplastic Agents / therapeutic use
  • Cell Line, Tumor
  • Drug Discovery
  • Humans
  • Immunoconjugates / chemistry*
  • Immunoconjugates / pharmacology*
  • Immunoconjugates / therapeutic use
  • Kinesins / antagonists & inhibitors*
  • Neoplasms / drug therapy
  • Pyrroles / chemistry*
  • Pyrroles / pharmacology*
  • Pyrroles / therapeutic use

Substances

  • Antineoplastic Agents
  • Immunoconjugates
  • KIF11 protein, human
  • Pyrroles
  • Kinesins