Tuning Charge Transport in Aromatic-Ring Single-Molecule Junctions via Ionic-Liquid Gating

Achieving gate control with atomic precision, which is crucial to the transistor performance on the smallest scale, remains a challenge. Herein we report a new class of aromatic-ring molecular nanotransistors based on graphene-molecule-graphene single-molecule junctions by using an ionic-liquid gate. Experimental phenomena and theoretical calculations confirm that this ionic-liquid gate can effectively modulate the alignment between molecular frontier orbitals and the Fermi energy level of graphene electrodes, thus tuning the charge-transport properties of the junctions. In addition, with a small gate voltage (|V_G |≤1.5 V) ambipolar charge transport in electrochemically inactive molecular systems (E_G >3.5 eV) is realized. These results offer a useful way to build high-performance single-molecule transistors, thus promoting the prospects for molecularly engineered electronic devices.