Inorganic Triphenylphosphine

A completely inorganic version of one of the most famous organophosphorus compounds, triphenylphosphine, has been prepared. A comparison of the crystal structures of inorganic triphenylphosphine, PBaz₃ (where Baz=B₃ H₂ N₃ H₃ ) and PPh₃ shows that they have superficial similarities and furthermore, the Lewis basicities of the two compounds are remarkably similar. However, their oxygenation and hydrolysis reactions are starkly different. PBaz₃ reacts quantitatively with water to give PH₃ and with the oxidizing agent ONMe₃ to give the triply-O-inserted product P(OBaz)₃ , an inorganic version of triphenyl phosphite; a corresponding transformation with PPh₃ is inconceivable. Thermodynamically, what drives these striking differences in the chemistry of PBaz₃ and PPh₃ is the great strength of the B-O bond.