Self-assembling supramolecular dendrimer nanosystem for PET imaging of tumors

Proc Natl Acad Sci U S A. 2018 Nov 6;115(45):11454-11459. doi: 10.1073/pnas.1812938115. Epub 2018 Oct 22.

Abstract

Bioimaging plays an important role in cancer diagnosis and treatment. However, imaging sensitivity and specificity still constitute key challenges. Nanotechnology-based imaging is particularly promising for overcoming these limitations because nanosized imaging agents can specifically home in on tumors via the "enhanced permeation and retention" (EPR) effect, thus resulting in enhanced imaging sensitivity and specificity. Here, we report an original nanosystem for positron emission tomography (PET) imaging based on an amphiphilic dendrimer, which bears multiple PET reporting units at the terminals. This dendrimer is able to self-assemble into small and uniform nanomicelles, which accumulate in tumors for effective PET imaging. Benefiting from the combined dendrimeric multivalence and EPR-mediated passive tumor targeting, this nanosystem demonstrates superior imaging sensitivity and specificity, with up to 14-fold increased PET signal ratios compared with the clinical gold reference 2-fluorodeoxyglucose ([18F]FDG). Most importantly, this dendrimer system can detect imaging-refractory low-glucose-uptake tumors that are otherwise undetectable using [18F]FDG. In addition, it is endowed with an excellent safety profile and favorable pharmacokinetics for PET imaging. Consequently, this dendrimer nanosystem constitutes an effective and promising approach for cancer imaging. Our study also demonstrates that nanotechnology based on self-assembling dendrimers provides a fresh perspective for biomedical imaging and cancer diagnosis.

Keywords: EPR effect; bioimaging; dendrimer; supramolecular nanomicelle; tumor diagnosis.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Cell Line, Tumor
  • Colonic Neoplasms / diagnostic imaging*
  • Colonic Neoplasms / pathology
  • Contrast Media / chemistry
  • Contrast Media / pharmacokinetics
  • Coordination Complexes / blood
  • Coordination Complexes / chemistry
  • Coordination Complexes / pharmacokinetics*
  • Dendrimers / chemistry
  • Fluorodeoxyglucose F18 / chemistry
  • Gallium Radioisotopes / blood
  • Gallium Radioisotopes / chemistry
  • Gallium Radioisotopes / pharmacokinetics*
  • Glioblastoma / diagnostic imaging*
  • Glioblastoma / pathology
  • Heterocyclic Compounds / chemistry
  • Heterocyclic Compounds, 1-Ring
  • Heterografts
  • Humans
  • Male
  • Mice
  • Mice, Inbred BALB C
  • Mice, Nude
  • Pancreatic Neoplasms / diagnostic imaging*
  • Pancreatic Neoplasms / pathology
  • Positron-Emission Tomography / methods*
  • Prostatic Neoplasms / diagnostic imaging*
  • Prostatic Neoplasms / pathology

Substances

  • Contrast Media
  • Coordination Complexes
  • Dendrimers
  • Gallium Radioisotopes
  • Heterocyclic Compounds
  • Heterocyclic Compounds, 1-Ring
  • Fluorodeoxyglucose F18
  • 1,4,7-triazacyclononane-N,N',N''-triacetic acid