Anti-hypertensive mechanisms of cyclic depsipeptide inhibitor ligands for Gq/11 class G proteins

Pharmacol Res. 2019 Mar:141:264-275. doi: 10.1016/j.phrs.2019.01.012. Epub 2019 Jan 10.

Abstract

Augmented vasoconstriction is a hallmark of hypertension and is mediated partly by hyper-stimulation of G protein couple receptors (GPCRs) and downstream signaling components. Although GPCR blockade is a key component of current anti-hypertensive strategies, whether hypertension is better managed by directly targeting G proteins has not been thoroughly investigated. Here, we tested whether inhibiting Gq/11 proteins in vivo and ex vivo using natural cyclic depsipeptide, FR900359 (FR) from the ornamental plant, Ardisia crenata, and YM-254890 (YM) from Chromobacterium sp. QS3666, or it's synthetic analog, WU-07047 (WU), was sufficient to reverse hypertension in mice. All three inhibitors blocked G protein-dependent vasoconstriction, but to our surprise YM and WU and not FR inhibited K+-induced Ca2+ transients and vasoconstriction of intact vessels. However, each inhibitor blocked whole-cell L-type Ca2+ channel current in vascular smooth muscle cells. Subcutaneous injection of FR or YM (0.3 mg/kg, s.c.) in normotensive and hypertensive mice elicited bradycardia and marked blood pressure decrease, which was more severe and long lasting after the injection of FR relative to YM (FRt1/2 ≅ 12 h vs. YMt1/2 ≅ 4 h). In deoxycorticosterone acetate (DOCA)-salt hypertension mice, chronic injection of FR (0.3 mg/kg, s.c., daily for seven days) reversed hypertension (vehicle SBP: 149 ± 5 vs. FR SBP: 117 ± 7 mmHg), without any effect on heart rate. Our results together support the hypothesis that increased LTCC and Gq/11 activity is involved in the pathogenesis of hypertension, and that dual targeting of both proteins can reverse hypertension and associated cardiovascular disorders.

Keywords: Arginine vasopressin (CID: 644077); Bay K8644 (CID: 2303; Blood pressure; Calcium signaling; Cyclic depsipeptides; Endothelin-1 (CID: 16212950); FR900359 (CID: 14101198); G proteins; G(q/11) inhibitor ligands; L-type calcium channel; Nifedipine (CID: 63011); Phenylephrine (CID: 5284443); U46619 (CID: 5311493); WU-07047 (PMID: 25875152); YM-254890 (CID: 9919454).

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Antihypertensive Agents / chemistry
  • Antihypertensive Agents / therapeutic use*
  • Ardisia / chemistry
  • Chromobacterium / chemistry
  • Depsipeptides / chemistry
  • Depsipeptides / therapeutic use*
  • Female
  • GTP-Binding Protein alpha Subunits, Gq-G11 / antagonists & inhibitors
  • GTP-Binding Protein alpha Subunits, Gq-G11 / metabolism*
  • Hypertension / drug therapy*
  • Hypertension / metabolism
  • Hypertension / physiopathology
  • Ligands
  • Male
  • Mice
  • Mice, Inbred C57BL
  • Peptides, Cyclic / chemistry
  • Peptides, Cyclic / therapeutic use*
  • Vasoconstriction / drug effects

Substances

  • Antihypertensive Agents
  • Depsipeptides
  • FR900359
  • Ligands
  • Peptides, Cyclic
  • YM-254890
  • GTP-Binding Protein alpha Subunits, Gq-G11