Carbon nitride as a ligand: edge-site coordination of ReCl(CO)3-fragments to g-C3N4

Chem Commun (Camb). 2019 Jul 4;55(52):7450-7453. doi: 10.1039/c9cc02197c. Epub 2019 Jun 11.

Abstract

IR spectroscopy and model structural studies show binding of ReCl(CO)3-fragments to carbon nitride (g-C3N4) occurs viaκ2 N,N' bidentate coordination.