The Methylene-Cycloalkylacetate (MCA) Scaffold in Terpenyl Compounds with Potential Pharmacological Activities

Molecules. 2019 Jun 5;24(11):2120. doi: 10.3390/molecules24112120.

Abstract

Recently, the methylene-cycloakylacetate (MCA) scaffold has been reported as a potential pharmacophore for neurite outgrowth activity. In this work, natural diterpenes that embed MCA fragments are reviewed, as they are major components of Halimium viscosum: ent-halimic acid, the prototype for these bioactive compounds. Herein, structures, sources, and activities for the natural diterpenes, as well as their synthetic derivatives of interest, are reviewed.

Keywords: MCA; ent-halimic acid; halimanes; methylene-cycloalkylacetate; neurotrophic.

Publication types

  • Review

MeSH terms

  • Acetates / chemistry*
  • Acetates / pharmacology*
  • Diterpene Alkaloids / chemistry
  • Diterpenes / chemical synthesis
  • Diterpenes / chemistry
  • Diterpenes / pharmacology
  • Glycerol / chemistry
  • Sesquiterpenes / chemistry
  • Terpenes / chemical synthesis
  • Terpenes / chemistry*
  • Terpenes / pharmacology*

Substances

  • Acetates
  • Diterpene Alkaloids
  • Diterpenes
  • Sesquiterpenes
  • Terpenes
  • ent-halimic acid
  • Glycerol