Rational Design, Structure-Activity Relationship, and Immunogenicity of Hypoallergenic Pru p 3 Variants

Mol Nutr Food Res. 2019 Sep;63(18):e1900336. doi: 10.1002/mnfr.201900336. Epub 2019 Jun 26.

Abstract

Scope: Allergies to lipid transfer proteins involve severe adverse reactions; thus, effective and sustainable therapies are desired. Previous attempts disrupting disulfide bonds failed to maintain immunogenicity; thus, the aim is to design novel hypoallergenic Pru p 3 variants and evaluate the applicability for treatment of peach allergy.

Methods and results: Pru p 3 proline variant (PV) designed using in silico mutagenesis, cysteine variant (CV), and wild-type Pru p 3 (WT) are purified from Escherichia coli. Variants display homogenous and stable protein conformations with an altered secondary structure in circular dichroism. PV shows enhanced long-term storage capacities compared to CV similar to the highly stable WT. Using sera of 33 peach allergic patients, IgE-binding activity is reduced by 97% (PV) and 71% (CV) compared to WT. Both molecules show strong hypoallergenicity in Pru p 3 ImmunoCAP cross-inhibition and histamine release assays. Immunogenicity of PV is demonstrated with a phosphate-based adjuvant formulation in a mouse model.

Conclusions: An in silico approach is used to generate a PV without targeting disulfide bonds, T cell epitopes, or previously reported IgE epitopes of Pru p 3. PV is strongly hypoallergenic while structurally stable and immunogenic, thus representing a promising candidate for peach allergen immunotherapy.

Keywords: Pru p 3; allergen immunotherapy; hypoallergens; lipid transfer proteins; peach allergies.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adolescent
  • Adult
  • Animals
  • Antigens, Plant / chemistry*
  • Antigens, Plant / genetics
  • Antigens, Plant / immunology*
  • Child
  • Disease Models, Animal
  • Female
  • Food Hypersensitivity*
  • Humans
  • Immunization
  • Immunoglobulin E / blood
  • Immunoglobulin E / metabolism
  • Mice, Inbred BALB C
  • Plant Proteins / chemistry*
  • Plant Proteins / genetics
  • Plant Proteins / immunology*
  • Recombinant Proteins / chemistry
  • Recombinant Proteins / genetics
  • Recombinant Proteins / immunology*
  • Structure-Activity Relationship
  • Young Adult

Substances

  • Antigens, Plant
  • Plant Proteins
  • Pru p 3 allergen
  • Recombinant Proteins
  • Immunoglobulin E