Does atmospheric processing produce toxic Pb-containing compounds? A case study in suburban Beijing by single particle mass spectrometry

A single particle aerosol mass spectrometry (SPAMS) was deployed to investigate the mixing state and chemical processing of Pb-rich particles in suburban Beijing. Based on a large dataset of mass spectra, Pb-rich particles were classified into Pb-O-Cl-N-S (55%), Pb-N (17%), Pb-N-S (15%), and Pb-EC (7%). Residual coal combustion, industrial activities, and meteorological conditions were identified as main factors regulating the variations of Pb-rich particles in the atmosphere. The highest abundance of the Pb-rich particles was observed during heating period (HP) primarily due to the increase in coal usage. Pb in Pb-O-Cl-N-S type was identified in forms of PbO, PbCl_2, and Pb(NO₃)₂. Dominantly presented in the form of Pb(NO₃)₂, Pb-N type represented the completely transformed Pb-rich particles from PbO/PbCl₂ by atmospheric processes. It is found that PbCl₂ and PbO could be transformed to Pb(NO₃)₂, highly dependent on the amount of NO₂ and RH. Significant enhancement of nitrate in Pb-O-Cl-N-S particles was observed when the RH was greater than 60%, emphasizing the importance of heterogeneous hydrolysis of N₂O₅ on the formation of Pb(NO₃)_2. Compared with non-carcinogenic PbCl₂/PbO and insoluble PbO, soluble and carcinogenic Pb(NO₃)₂ produced by atmospheric processes may significantly enhance negative effects of Pb-rich particles on human health and the ecosystem.