A portable on-axis laser-heating system for near-90° X-ray spectroscopy: application to ferropericlase and iron silicide

J Synchrotron Radiat. 2020 Mar 1;27(Pt 2):414-424. doi: 10.1107/S1600577519017041. Epub 2020 Feb 13.

Abstract

A portable IR fiber laser-heating system, optimized for X-ray emission spectroscopy (XES) and nuclear inelastic scattering (NIS) spectroscopy with signal collection through the radial opening of diamond anvil cells near 90°with respect to the incident X-ray beam, is presented. The system offers double-sided on-axis heating by a single laser source and zero attenuation of incoming X-rays other than by the high-pressure environment. A description of the system, which has been tested for pressures above 100 GPa and temperatures up to 3000 K, is given. The XES spectra of laser-heated Mg0.67Fe0.33O demonstrate the potential to map the iron spin state in the pressure-temperature range of the Earth's lower mantle, and the NIS spectra of laser-heated FeSi give access to the sound velocity of this candidate of a phase inside the Earth's core. This portable system represents one of the few bridges across the gap between laser heating and high-resolution X-ray spectroscopies with signal collection near 90°.

Keywords: X-ray emission spectroscopy; extreme conditions; high pressure; laser heating; nuclear resonant inelastic scattering.