On-off Fluorescent Switching of Excitation-independent Near-ultraviolet Emission Carbon Nanobelts for Ultrasensitive Detection Nimesulide in Pharmaceutical Tablet

Anal Sci. 2020 Nov 10;36(11):1379-1383. doi: 10.2116/analsci.20P181. Epub 2020 Jul 10.

Abstract

Here, we present an excellent strategy of unmodified near-ultraviolet fluorescence nitrogen doping carbon nanobelts (NFNCBs) for detecting nimesulide (Nim). After a simple hydrothermal process of uric acid and hydroquinone in DMF solvent, NFNCBs shows the shape of corroded stalactite-like composed of nanobelts aggregates, near-ultraviolet luminescence and a narrowed full width at half maximum. This could improve/change the electronic properties and surface chemical active site, as the result of a sensitive response to Nim. By employing this sensor, the quantitative measurement displays a linear range of 2.0 nM - 100.0 μM with a lower detection limit of 0.21 nM (3σ/k) for Nim. Our work has provided a high selectivity for Nim, which may be capable for pharmaceutical sample analysis in real tablets. Furthermore, the results concerning the recoveries (96.3 - 106.2%) for real sample analysis indicate that this nanoprobe might expand a good avenue to design an effective luminescence nanoprobe for other biologically related drugs.

Keywords: Carbon nanobelts; near-ultraviolet luminescence; nimesulide; pharmaceutical sample.

MeSH terms

  • Carbon / chemistry*
  • Limit of Detection*
  • Linear Models
  • Nanostructures / chemistry*
  • Spectrometry, Fluorescence*
  • Sulfonamides / analysis*
  • Sulfonamides / chemistry
  • Tablets / chemistry
  • Ultraviolet Rays*

Substances

  • Sulfonamides
  • Tablets
  • Carbon
  • nimesulide