Chain reactions: molecular mechanisms of RBR ubiquitin ligases

Biochem Soc Trans. 2020 Aug 28;48(4):1737-1750. doi: 10.1042/BST20200237.

Abstract

Ubiquitination is a fundamental post-translational modification that regulates almost all aspects of cellular signalling and is ultimately catalysed by the action of E3 ubiquitin ligases. The RING-between-RING (RBR) family of E3 ligases encompasses 14 distinct human enzymes that are defined by a unique domain organisation and catalytic mechanism. Detailed characterisation of several RBR ligase family members in the last decade has revealed common structural and mechanistic features. At the same time these studies have highlighted critical differences with respect to autoinhibition, activation and catalysis. Importantly, the majority of RBR E3 ligases remain poorly studied, and thus the extent of diversity within the family remains unknown. In this mini-review we outline the current understanding of the RBR E3 mechanism, structure and regulation with a particular focus on recent findings and developments that will shape the field in coming years.

Keywords: RBR ubiquitin ligases; enzyme activity; post-translational modification; ubiquitin ligases; ubiquitin signalling.

Publication types

  • Research Support, Non-U.S. Gov't
  • Review

MeSH terms

  • Allosteric Regulation
  • Amino Acid Sequence
  • Binding Sites
  • Catalysis
  • Protein Conformation
  • Sequence Homology, Amino Acid
  • Ubiquitin / metabolism
  • Ubiquitin-Protein Ligases / antagonists & inhibitors
  • Ubiquitin-Protein Ligases / metabolism*
  • Ubiquitination

Substances

  • Ubiquitin
  • Ubiquitin-Protein Ligases