UHPLC-MS/MS method for iohexol determination in human EDTA and lithium-heparin plasma, human urine and in goat- and pig EDTA plasma

Bioanalysis. 2020 Jul;12(14):981-990. doi: 10.4155/bio-2020-0122. Epub 2020 Jul 22.

Abstract

Aim: Iohexol plasma clearance is used as an indicator of kidney function in clinical and preclinical settings. To investigate the pharmacokinetic profile of iohexol, a rapid, simple method for measurement of iohexol in different matrices and species was needed. Materials & methods: Iohexol was separated on an Accucore C18 column (Thermo Fisher Scientific, CA, USA). Detection was performed on a Thermo Scientific Quantiva tandem quadrupole mass spectrometer. The method was validated according to the requirements for bioanalytical methods issued by the US FDA and European Medicines Agency. Conclusion: We developed and validated a fast and efficient analytical method, suitable for analyzing iohexol in human EDTA plasma, human lithium-heparin plasma, human urine and goat- and pig EDTA plasma, using only one calibration line prepared in human EDTA plasma.

Keywords: LC–MS/MS; goat plasma; human plasma; human urine; iohexol; pig plasma.

MeSH terms

  • Animals
  • Chromatography, High Pressure Liquid / methods*
  • Edetic Acid / chemistry*
  • Goats
  • Heparin / blood*
  • Humans
  • Iohexol / chemistry*
  • Lithium / blood*
  • Lithium / chemistry
  • Swine
  • Tandem Mass Spectrometry / methods*

Substances

  • Iohexol
  • Heparin
  • Lithium
  • Edetic Acid