Decolorization and detoxification of azo dye by halo-alkaliphilic bacterial consortium: Systematic investigations of performance, pathway and metagenome

Ecotoxicol Environ Saf. 2020 Nov:204:111073. doi: 10.1016/j.ecoenv.2020.111073. Epub 2020 Aug 2.

Abstract

The high pH and salinity of textile wastewater is a major hindrance to azo dye decolorization. In this study, a mixed bacterial consortium ZW1 was enriched under saline (10% salinity) and alkaline (pH 10.0) conditions to decolorize Methanil Yellow G (MY-G). Consortium ZW1 was mainly composed of Halomonas (49.8%), Marinobacter (30.7%) and Clostridiisalibacter (19.2%). The effects of physicochemical factors were systematically investigated, along with the degradation pathway and metagenome analysis. The co-carbon source was found to be necessary, and the addition of yeast extract led to 93.3% decolorization of 100 mg/L MY-G within 16 h (compared with 1.12% for control). The optimum pH, salinity, temperature and initial dye concentration were 8.0, 5-10%, 40 °C and 100 mg/L, respectively. The typical dye-related degradation enzymes were most effective at 10% salinity. Consortium ZW1 was also able to differentially decolorize five other direct and acidic dyes in a short period. Phototoxicity tests revealed the detoxification of MY-G degradation products. Combining UV-vis, FTIR and GC-MS detection, the MY-G degradation pathway by consortium ZW1 was proposed. Furthermore, metagenomic approach was used to elucidate the functional potential of genes in MY-G biodegradation. These results signify the broad potential application of halo-alkaliphilic consortia in the bioremediation of dyeing wastewater.

Keywords: Azo dye; Degradation pathway; Halo-alkaliphilic; Metagenome; Mixed bacterial consortium.

MeSH terms

  • Azo Compounds / metabolism
  • Azo Compounds / toxicity*
  • Biodegradation, Environmental
  • Carbon / metabolism
  • Coloring Agents / metabolism
  • Coloring Agents / toxicity*
  • Metagenome*
  • Microbiota / drug effects*
  • Microbiota / genetics
  • Salinity
  • Temperature
  • Textile Industry
  • Wastewater* / chemistry
  • Wastewater* / microbiology
  • Water Pollutants, Chemical / metabolism
  • Water Pollutants, Chemical / toxicity*
  • Water Purification / methods*

Substances

  • Azo Compounds
  • Coloring Agents
  • Waste Water
  • Water Pollutants, Chemical
  • Carbon