High-performance liquid chromatographic column-switching method for two cyclosporine metabolites in blood

J Chromatogr. 1988 Mar 18;425(2):343-52. doi: 10.1016/0378-4347(88)80038-0.

Abstract

Cyclosporine (CSA) is biotransformed to many metabolites which may contribute to its immunosuppressive and nephrotoxic activity. We report a rapid and sensitive, automated column-switching high-performance liquid chromatographic (HPLC) method for measuring CSA-M17 in whole blood; the method also separates CSA-M1. CSA metabolite standards were isolated by a preparative-scale HPLC method. Samples were prepared by protein precipitation with acetonitrile followed by dilution with water. CSA-M17 was initially separated on a C8 column; final separation was on a C18 column. The inter-day relative standard deviation at 50 ng/ml was 8% (n = 3). Limit of detection was 20 ng/ml.

Publication types

  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Biotransformation
  • Bone Marrow Transplantation
  • Chromatography, High Pressure Liquid
  • Cyclosporins / blood*
  • Humans
  • Indicators and Reagents
  • Magnetic Resonance Spectroscopy
  • Male

Substances

  • Cyclosporins
  • Indicators and Reagents