Identification of residues important for M. tuberculosis MmpL11 function reveals that function is modulated by phosphorylation in the C-terminal domain

Mol Microbiol. 2021 Feb;115(2):208-221. doi: 10.1111/mmi.14611. Epub 2020 Nov 3.

Abstract

The Mycobacterium tuberculosis cell envelope is a critical interface between the host and pathogen and provides a protective barrier against the immune response and antibiotics. Cell envelope lipids are also mycobacterial virulence factors that influence the host immune response. The mycobacterial membrane protein large (MmpL) proteins transport cell envelope lipids and siderophores that are important for the basic physiology and pathogenesis of M. tuberculosis. We recently identified MmpL11 as a conserved transporter of mycolic acid-containing lipids including monomeromycolyl diacylglycerol (MMDAG), mycolate wax ester (MWE), and long-chain triacylglycerols (LC-TAGs). These lipids contribute to biofilm formation in M. tuberculosis and M. smegmatis, and non-replicating persistence in M. tuberculosis. In this report, we identified domains and residues that are essential for MmpL11TB lipid transporter activity. Specifically, we show that the D1 periplasmic loop and a conserved tyrosine are essential for the MmpL11 function. Intriguingly, we found that MmpL11 levels are regulated by the phosphorylation of threonine in the cytoplasmic C-terminal domain, providing the first direct evidence of the phospho-regulation of MmpL11 transporter activity in M. tuberculosis and M. smegmatis. Our results offer further insight into the function of MmpL transporters and regulation of mycobacterial cell envelope biogenesis.

Keywords: Mycobacterium tuberculosis; MmpL transporter; biofilm; mycolic acid; serine-threonine protein kinase.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Bacterial Proteins / metabolism
  • Biological Transport
  • Carrier Proteins / metabolism
  • Cell Membrane / metabolism
  • Cell Wall / metabolism
  • Membrane Proteins / metabolism
  • Membrane Transport Proteins / metabolism*
  • Membrane Transport Proteins / physiology
  • Mycobacterium tuberculosis / metabolism*
  • Mycolic Acids / metabolism
  • Periplasm / metabolism
  • Phosphorylation
  • Siderophores / metabolism
  • Tuberculosis / microbiology
  • Virulence Factors / metabolism

Substances

  • Bacterial Proteins
  • Carrier Proteins
  • Membrane Proteins
  • Membrane Transport Proteins
  • Mycolic Acids
  • Siderophores
  • Virulence Factors