Triphenyl-imidazole based reversible coloro/fluorimetric sensing and electrochemical removal of Cu²⁺ ions using capacitive deionization and molecular logic gates

A simple hydroxyl-substituted triphenyl-imidazole based receptor (HTPI) which selectively detects Cu²⁺ ion by colorimetric and fluorimetric methods was developed. HTPI detects the Cu²⁺ ions with the absorption enhancement and fluorescence quenching by the possible ligand to metal charge transfer (LMCT) and the chelation-enhanced quenching (CHEQ) approaches, respectively. HTPI showed high selectivity and sensitivity for Cu²⁺ ions detection over other interfering and competing metal ions. Interestingly, HTPI detects Cu²⁺ ion (LOD) at nanomolar concentrations (19 × 10^-9 M (UV-vis) & 27 × 10^-9 M (fluorescence), respectively), which is lower than the permissible level of Cu²⁺ ion reported by World Health Organization (WHO). Furthermore, HTPI was applied to the molecular logic gate function by using chemical inputs, and Cu²⁺ ion was potentially removed (95%) via Capacitive Deionization technique.