N-phenyl-1-naphthylamine (PNA) Accumulates in Snapping Turtle (Chelydra serpentina) Liver Activating the Detoxification Pathway

Bull Environ Contam Toxicol. 2020 Dec;105(6):813-818. doi: 10.1007/s00128-020-03043-0. Epub 2020 Nov 19.

Abstract

Substituted phenylamine antioxidants (SPAs) are used in Canadian industrial processes. SPAs, specifically N-phenyl-1-naphthylamine (PNA), have received very little attention despite their current use in Canada and their expected aquatic and environmental releases. There is a research gap regarding the effects of PNA in wildlife; therefore, Chelydra serpentina (common snapping turtle) was studied due to its importance as an environmental indicator species. A chronic experiment was performed using PNA spiked food (0 to 3446 ng/g) to determine its toxicity to juvenile C. serpentina. A significant increase in cyp1a mRNA level was observed in the liver of turtles exposed to 3446 ng/g PNA, suggesting that phase I detoxification is activated in the exposed animals. Additionally, a significant decrease in cyp2b transcript level was observed at the two lowest PNA doses, likely indicating another metabolic alteration for PNA. This study helped determine the molecular effects associated with a PNA exposure in reptiles.

Keywords: Cytochrome P450; Metabolism; N-phenyl-1-naphthylamine; Toxicity; Turtle.

MeSH terms

  • 1-Naphthylamine / analogs & derivatives*
  • 1-Naphthylamine / metabolism
  • Animals
  • Animals, Wild
  • Canada
  • Liver
  • Reptiles
  • Turtles / metabolism*

Substances

  • N-phenyl-1-naphthylamine
  • 1-Naphthylamine