Phytochemical Constituents of Citrus hystrix DC. Leaves Attenuate Inflammation via NF-κB Signaling and NLRP3 Inflammasome Activity in Macrophages

Biomolecules. 2021 Jan 14;11(1):105. doi: 10.3390/biom11010105.

Abstract

Citrus hystrix DC. (CH) is found in many countries in Southeast Asia. This plant has been reported for anti-microbial, anti-cancer and anti-inflammatory bioactivities. However, the anti-inflammatory and anti-inflammasome properties of the leaves remain poorly understood. This study aimed to investigate the effect of CH leaves on NLRP3 and NF-κB signaling pathways. CH leaves were sequentially extracted using hexane, ethyl acetate and 95% ethanol to give three crude extracts. An active compound, lupeol was fractionated from the ethanolic extract using chromatographic techniques, and its structure was identified and confirmed by spectroscopic methods. Anti-inflammatory activities were observed on both lipopolysaccharide-stimulated and NLRP3 adenosine triphosphate-induced macrophages. The release of pro-inflammatory cytokines (IL-1β, IL-6 and TNF-α) was analyzed by Enzyme-Linked Immunosorbent Assay (ELISA). Real-time qRT-polymerase chain reaction (PCR) was used to measure inflammatory-associated gene expression. NF-κB protein expressions were investigated using the immunoblotting technique. The active fraction of ethanolic CH leaves and lupeol significantly reduced the release of pro-inflammatory cytokines and suppressed the expression of both inflammasome genes and NF-κB proteins. The ethanolic extract of CH leaves and lupeol showed potent anti-inflammatory activities by targeting NF-κB and NLRP3 signaling pathways.

Keywords: Citrus hystrix; NF-κB; NLRP3; inflammasome; lupeol; macrophage.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Anti-Inflammatory Agents / pharmacology
  • Antigens, CD / metabolism
  • Biomarkers / metabolism
  • Cell Membrane / drug effects
  • Cell Membrane / metabolism
  • Citrus / chemistry*
  • Complex Mixtures
  • Cyclooxygenase 2 / metabolism
  • Humans
  • Inflammasomes / metabolism*
  • Inflammation / drug therapy*
  • Inflammation / metabolism
  • Inflammation Mediators / metabolism
  • Lipopolysaccharides
  • Macrophages / drug effects
  • Macrophages / metabolism*
  • NF-KappaB Inhibitor alpha
  • NF-kappa B / metabolism*
  • NLR Family, Pyrin Domain-Containing 3 Protein / metabolism*
  • Pentacyclic Triterpenes / chemistry
  • Pentacyclic Triterpenes / pharmacology
  • Phosphorylation / drug effects
  • Phytochemicals / isolation & purification
  • Phytochemicals / pharmacology
  • Phytochemicals / therapeutic use*
  • Plant Leaves / chemistry*
  • RNA, Messenger / genetics
  • RNA, Messenger / metabolism
  • Signal Transduction / drug effects
  • THP-1 Cells

Substances

  • Anti-Inflammatory Agents
  • Antigens, CD
  • Biomarkers
  • Complex Mixtures
  • Inflammasomes
  • Inflammation Mediators
  • Lipopolysaccharides
  • NF-kappa B
  • NLR Family, Pyrin Domain-Containing 3 Protein
  • Pentacyclic Triterpenes
  • Phytochemicals
  • RNA, Messenger
  • NF-KappaB Inhibitor alpha
  • Cyclooxygenase 2
  • lupeol