Construction of magnetically recoverable ZnS-WO₃-CoFe₂O₄ nanohybrid enriched photocatalyst for the degradation of MB dye under visible light irradiation

Easily recyclable photocatalysts have received considerable attention for their practical application, in order to address the wastewater treatments. Here, we report efficient and magnetically recyclable ZnS-WO₃-CoFe₂O₄ nanohybrid prepared through wet impregnation method. The photophysical and optical properties of as-prepared photocatalysts was investigated by different spectroscopic techniques. The photocatalytic activity of as synthesized samples were assessed by the photodegradation of methylene blue (MB) dye under visible light irradiation. Amongst, ZnS-WO₃-CoFe₂O₄ nanohybrid exhibit higher photodegradation activity than the other bare and hybrid samples. The enhanced light absorption and lower emission intensity provide the improved photocatalytic activity of ZnS-WO₃-CoFe₂O₄ nanohybrid. The ZnS-WO₃-CoFe₂O₄ nanohybrid exhibit excellent photostability after four consecutive cycles. The ferromagnetic behavior of the hybrid sample using easily recover from the dye solution using an external bar magnet.