Silica-Organometallic One-Dimensional Hybrid Employing a Ag-πC═C Bond Connecting Alternating Ag4(NO3)4 and Octavinylsilsesquioxane

Zhi Wang; Mo Ashafaq; Yu-Fan Lu; Lei Feng; Mohamedally Kurmoo; Hongzhi Liu; Zhi-Yong Gao; Yun-Wu Li; Di Sun

doi:10.1021/acs.inorgchem.1c00160

Silica-Organometallic One-Dimensional Hybrid Employing a Ag-π_C═C Bond Connecting Alternating Ag₄(NO₃)₄ and Octavinylsilsesquioxane

Inorg Chem. 2021 Mar 1;60(5):2899-2904. doi: 10.1021/acs.inorgchem.1c00160. Epub 2021 Feb 16.

Authors

Zhi Wang¹, Mo Ashafaq², Yu-Fan Lu¹, Lei Feng¹, Mohamedally Kurmoo³, Hongzhi Liu¹, Zhi-Yong Gao⁴, Yun-Wu Li⁵, Di Sun¹

Affiliations

¹ Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, State Key Laboratory of Crystal Materials, Shandong University, Ji'nan 250100, People's Republic of China.
² Department of Chemistry, Aligarh Muslim University, Aligarh 202002, India.
³ Institut de Chimie de Strasbourg, Université Strasbourg, CNRS, UMR 7177, 4 rue Blaise Pascal, 67008 Strasbourg, Cedex, France.
⁴ School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Henan Normal University, Henan Xinxiang 453007, People's Republic of China.
⁵ Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, and School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, China.

PMID: 33591171
DOI: 10.1021/acs.inorgchem.1c00160

Abstract

Layering AgNO₃ in alcohol onto octavinylsilsesquioxane (OVS) in CHCl₃ results in a one-dimensional coordination polymer, {Ag₄(NO₃)₄(OVS)·solvents}_n (SD/Ag4a-d), consisting of unprecedented flat weakly bonded Ag₄(NO₃)₄ alternating with the firmly covalent OVS through Ag^I-π_C═C bonds. The preferential assembling medium for SD/Ag4a is proven to be alcohols, where a 4:1 silver-OVS adduct is detected by electrospray ionization mass spectrometry. The present outcomes may assist our knowledge of particular interactions for supramolecular architectures of a polynuclear silver system built from OVS containing eight pendent olefin tails.