Engineering and crystal structure of a monomeric FLT3 ligand variant

Acta Crystallogr F Struct Biol Commun. 2021 Apr 1;77(Pt 4):121-127. doi: 10.1107/S2053230X21003289. Epub 2021 Apr 6.

Abstract

The overarching paradigm for the activation of class III and V receptor tyrosine kinases (RTKs) prescribes cytokine-mediated dimerization of the receptor ectodomains and homotypic receptor-receptor interactions. However, structural studies have shown that the hematopoietic receptor FLT3, a class III RTK, does not appear to engage in such receptor-receptor contacts, despite its efficient dimerization by dimeric FLT3 ligand (FL). As part of efforts to better understand the intricacies of FLT3 activation, we sought to engineer a monomeric FL. It was found that a Leu27Asp substitution at the dimer interface of the cytokine led to a stable monomeric cytokine (FLL27D) without abrogation of receptor binding. The crystal structure of FLL27D at 1.65 Å resolution revealed that the introduced point mutation led to shielding of the hydrophobic footprint of the dimerization interface in wild-type FL without affecting the conformation of the FLT3 binding site. Thus, FLL27D can serve as a monomeric FL variant to further interrogate the assembly mechanism of extracellular complexes of FLT3 in physiology and disease.

Keywords: FLT3; FLT3 ligand; acute myeloid leukemia; receptor tyrosine kinases.

MeSH terms

  • Amino Acid Sequence
  • Genetic Variation / genetics*
  • HEK293 Cells
  • Humans
  • Membrane Proteins / chemistry
  • Membrane Proteins / genetics*
  • Membrane Proteins / metabolism
  • Protein Binding / physiology
  • Protein Engineering / methods*
  • Protein Structure, Secondary
  • Protein Structure, Tertiary
  • X-Ray Diffraction / methods*
  • fms-Like Tyrosine Kinase 3 / chemistry
  • fms-Like Tyrosine Kinase 3 / genetics*
  • fms-Like Tyrosine Kinase 3 / metabolism

Substances

  • Membrane Proteins
  • flt3 ligand protein
  • FLT3 protein, human
  • fms-Like Tyrosine Kinase 3

Grants and funding

This work was funded by Agentschap Innoveren en Ondernemen grant . Herculesstichting grant . Kom op tegen Kanker grant . Universiteit Gent, Bijzonder Onderzoeksfonds UGent grant . Vlaams Instituut voor Biotechnologie grant .