Well-to-wake analysis of switchgrass to jet fuel via a novel co-fermentation of sugars and CO₂

Lignocellulosic biomass such as switchgrass can be converted to n-butanol using fermentation, which can be further processed into jet fuel. Traditional acetone-butanol-ethanol (ABE) fermentation only converts sugars derived from switchgrass to ABE. Novel co-fermentation processes convert sugars and gas (CO₂/H₂) produced during fermentation into butanol, thus increasing ABE yields by 15.5% compared to traditional ABE fermentation. Herein, the environmental impact of a Switchgrass to Jet Fuel (STJ) pathway was assessed using life cycle assessment (LCA) from well-to-wake. LCAs were performed for greenhouse gas (GHG) emissions from jet fuel production via co-fermentation of sugars and gas for ideal and practical cases of ABE fermentation and seven other jet fuel pathways. The ideal case assumes 100% sugar recovery and 95% ABE yield. The practical case assumes 90% sugar recovery and an 80% ABE yield. Results are presented based on 100-year global warming potential (GWP) per MJ of jet fuel. Co-products were allocated using various methods. The increase in butanol yield via the co-fermentation technology reduced GWP-100 for the STJ pathway by 6.5% compared to traditional ABE fermentation. Similarly, the STJ pathway for the practical case with co-fermentation had 14.2%, 47.5%, 73.8%, and 44.4% less GWP-100 compared to HRJ, Fischer-Tropsch jet fuel from switchgrass, Fischer-Tropsch jet fuel from coal, and conventional petroleum jet fuel. The results demonstrate that the STJ pathway via co-fermentation has the potential to increase product yield while reducing GHG emissions compared to other jet fuel production pathways.