Improving Ammonia Detecting Performance of Polyaniline Decorated rGO Composite Membrane with GO Doping

Materials (Basel). 2021 May 25;14(11):2829. doi: 10.3390/ma14112829.

Abstract

Gas-sensing performance of graphene-based material has been investigated widely in recent years. Polyaniline (PANI) has been reported as an effective method to improve ammonia gas sensors' response. A gas sensor based on a composite of rGO film and protic acid doped polyaniline (PA-PANI) with GO doping is reported in this work. GO mainly provides NH3 adsorption sites, and PA-PANI is responsible for charge transfer during the gas-sensing response process. The experimental results indicate that the NH3 gas response of rGO is enhanced significantly by decorating with PA-PANI. Moreover, a small amount of GO mixed with PA-PANI is beneficial to increase the gas response, which showed an improvement of 262.5% at 25 ppm comparing to no GO mixing in PA-PANI.

Keywords: PA-PANI; composite membrane; gas sensor; graphene oxide; nanocomposites; protic acid doping; reduced graphene oxide.