Development of AC265347-Inspired Calcium-Sensing Receptor Ago-Positive Allosteric Modulators

ChemMedChem. 2021 Nov 19;16(22):3451-3462. doi: 10.1002/cmdc.202100368. Epub 2021 Jul 29.

Abstract

The calcium-sensing receptor (CaSR) is a clinical target in the treatment of hyperparathyroidism and related diseases. However, clinical use of approved CaSR-targeting drugs such as cinacalcet is limited due to adverse side effects including hypocalcaemia, nausea and vomiting, and in some instances, a lack of efficacy. The CaSR agonist and positive allosteric modulator (ago-PAM), AC265347, is chemically distinct from clinically-approved CaSR PAMs. AC265347 potently suppressed parathyroid hormone (PTH) release in rats with a lower propensity to cause hypocalcaemia compared to cinacalcet and may therefore offer benefits over current CaSR PAMs. Here we report a structure activity relationship (SAR) study seeking to optimise AC265347 as a drug candidate and disclose the discovery of AC265347-like compounds with diverse pharmacology and improved physicochemical and drug-like properties.

Keywords: AC265347; calcium-sensing receptor; class C GPCR; positive allosteric modulators; structure-activity relationship.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Allosteric Regulation / drug effects
  • Animals
  • Humans
  • Models, Molecular
  • Molecular Structure
  • Rats
  • Receptors, Calcium-Sensing* / agonists
  • Structure-Activity Relationship

Substances

  • Receptors, Calcium-Sensing
  • AC265347