Highly efficient catalytic reduction of 4-nitrophenol and organic dyes by ultrafine palladium nanoparticles anchored on CeO₂ nanorods

Uniformly dispersed Pd nanoparticles on certain supports exhibit exceptional catalytic performance toward various environmental applications. In this work, ultrafine Pd nanoparticles anchored on CeO₂ nanorods were synthesized via an absorption-in situ reduction method. The activity of the CeO₂/Pd nanocomposites was systematically investigated toward reduction of 4-nitrophenol (4-NP) and organic dyes including methyl blue, rhodamine B, methyl orange, and Congo red. The results indicated that the CeO₂/Pd nanocomposites with different weight ratios of Pd nanoparticles (10.23 wt%, 11.01 wt%, and 14.27 wt%) can almost completely reduce 4-NP with a rate constant of 3.31×10^-1, 3.22×10^-1, and 2.23×10^-1 min^-1. Besides, the 10.23 wt% CeO₂/Pd nanocomposites exhibit remarkable enhanced catalytic activity toward reduction of organic dyes. The catalysts display ideal stability after being used for three times for the reduction of 4-NP. We believe that our strategy demonstrated here offers insights into the design and fabrication of novel Pd-based nanocomposites for various heterogeneous catalysis applications.