Adsorption behavior of silver quantum dots by a novel super magnetic CoFe₂O₄-biochar-polymeric nanocomposite

Recent industrial development and research progress in nanotechnology have led to the release of a number of nanomaterials with particle sizes (1-10 nm) which are categorized as quantum dots (QDs) in aquatic system. Disposal away of such QDs will cause potential pollution to the environment. Therefore, removal of disposed QDs from wastewater represents a challenging research subject for scientists and engineers. Hence, the objective of this study is devoted to assess the process of coagulative removal of silver quantum dots (Ag-QDs), as an example, from water by a novel super magnetic nanocomposite. Such material was aimed to prepare from the chemical combination and reaction of a generated Citrus sinensis and Citrus reticulata peels biochar (SMCsr-B) with spinel cobalt ferrite (CoFe₂O₄) as a super-magnetic source. The produced (SMCsr-B) was then crosslinked with polyurea-formaldehyde polymer (PUF) using EDA in only two minutes via microwave irradiation to produce (SMCsr-B/PUF). The SEM, EDX, FT-IR, XRD, and XPS analyses of the assembled (SMCsr-B/PUF) nanocomposite were acquired to confirm surface morphology and chemical structure. Controlling experimental factors were investigated as pH, time, and Ag-QDs pollutant concentration using microwave irradiative removal technique to establish the efficiency of coagulative adsorption of Ag-QDs onto (SMCsr-B/PUF). The solution (pH 5) was proved to exhibit the higher removal percentages of Ag-QDs in 15-25 s. SMCsr-B/PUF nanocomposite exhibited high removal efficiency as 93.12%, 92.39% and 92.48% upon using 20, 40 and 60 mg L^-1 of Ag-QDs, respectively in presence of 10 mM NaCl. The kinetic and equilibrium adsorption data were best fitted to Freundlich model. The prepared SMCsr-B/PUF was successfully utilized as an efficient super magnetic nanocomposite for removal and recovery of Ag-QDs from aqueous environment.