Chemical analysis of fresh and aged Australian e-cigarette liquids

Med J Aust. 2022 Jan 17;216(1):27-32. doi: 10.5694/mja2.51280. Epub 2021 Oct 6.

Abstract

Objectives: To assess the chemical composition of electronic cigarette liquids (e-liquids) sold in Australia, in both their fresh and aged forms.

Design, setting: Gas chromatography-mass spectrometry analysis of commercial e-liquids sold in Australia (online and physical stores).

Main outcome measures: Chemical composition of 65 Australian e-liquids - excipients/solvents, flavouring chemicals, other known e-liquid constituents (including nicotine), and polycyclic aromatic hydrocarbons - before and after an accelerated ageing process that simulated the effects of vaping.

Results: The measured levels of propylene glycol and glycerol often diverged from those recorded on the e-liquid label. All e-liquids contained one or more potentially harmful chemicals, including benzaldehyde, menthol, trans-cinnamaldehyde, and polycyclic aromatic hydrocarbons. Nicotine or nicotyrine were detected in a small proportion of e-liquids at extremely low concentrations.

Conclusions: Australian e-liquids contain a wide variety of chemicals for which information on inhalation toxicity is not available. Further analyses are required to assess the potential long term effects of e-cigarette use on health.

Keywords: Analytic chemistry; Electronic cigarettes.

MeSH terms

  • Acrolein / analogs & derivatives
  • Acrolein / analysis
  • Acrolein / standards
  • Administration, Inhalation
  • Australia
  • Electronic Nicotine Delivery Systems / standards*
  • Flavoring Agents / analysis
  • Flavoring Agents / standards
  • Gas Chromatography-Mass Spectrometry
  • Nicotine / analysis
  • Nicotine / standards
  • Polycyclic Aromatic Hydrocarbons / analysis
  • Polycyclic Aromatic Hydrocarbons / standards
  • Product Labeling / standards*
  • Propylene Glycol / analysis
  • Propylene Glycol / standards

Substances

  • Flavoring Agents
  • Polycyclic Aromatic Hydrocarbons
  • Propylene Glycol
  • Nicotine
  • Acrolein
  • cinnamaldehyde