Synergistic combination of ACQ and AIE moieties to enhance the emission of hexagonal metallacycles

Bingzhao Wu; Zhewen Guo; Guangfeng Li; Jun Zhao; Yuhang Liu; Jinbing Wang; Huigang Wang; Xuzhou Yan

doi:10.1039/d1cc03787k

Synergistic combination of ACQ and AIE moieties to enhance the emission of hexagonal metallacycles

Chem Commun (Camb). 2021 Oct 21;57(84):11056-11059. doi: 10.1039/d1cc03787k.

Authors

Bingzhao Wu^{1

2}, Zhewen Guo², Guangfeng Li², Jun Zhao², Yuhang Liu², Jinbing Wang³, Huigang Wang¹, Xuzhou Yan²

Affiliations

¹ Department of Chemistry, Key Laboratory of Surface & Interface Science of Polymer Materials of Zhejiang Province, Zhejiang Sci-Tech University, Hangzhou 310018, P. R. China. [email protected].
² School of Chemistry and Chemical Engineering, Frontiers Science Centre for Transformative Molecules, Shanghai Jiao Tong University, Shanghai 200240, P. R. China. [email protected].
³ Department of Oral and Maxillofacial-Head and Neck Oncology, Shanghai Ninth People's Hospital, College of Stomatology, Shanghai Jiao Tong University School of Medicine, Shanghai Key Laboratory of Stomatology & Shanghai Research Institute of Stomatology, National Clinical Centre for Oral Disease, Shanghai, 200011, P. R. China. [email protected].

PMID: 34609386
DOI: 10.1039/d1cc03787k

Abstract

Herein, we show the synergistic combination of aggregation-caused quenching (ACQ) and aggregation-induced emission (AIE) units into two hexagonal metallacycles. The resultant metallacycles displayed emergent photophysical properties including tunable fluorescence using the polarity and solubility of the solvents as well as enhanced emissive efficacy. Our work demonstrates the synergistic enhancement of these two orthogonal effects via coordination-driven self-assembly.