Loading with micro-nanosized α-MnO₂ efficiently promotes the removal of arsenite and arsenate by biochar derived from maize straw waste: Dual role of deep oxidation and adsorption

The function of biochar (BC) as an eco-friendly adsorbent for environmental remediation is gaining much attention. However, the pristine BC had limited abilities for the removal of As (III, V). Towards this issue, this study synthesized biochar/micro-nanosized α-MnO₂ (BM) composites with different mass ratios of biochar to MnO₂. Comprehensive characterizations confirmed the successful loading of micro-nanosized α-MnO₂ onto the BC surface and the obvious specific surface area enhancement (7.5-13.5 times) of BM relative to BC. BM composites exhibited 5.0-13.0 folds higher removal capacity for As (III, V) than pristine BC since the composites gave full play to the oxidation contributed by micro-nanosized α-MnO₂ substrate and adsorption functions provided by the Mn-OH, BC-COOH, and BC-OH functional groups. Moreover, BM was well reused maintaining a relatively high removal efficiency for As (III, V). Regardless of reaction time and initial As (III) concentration (C₀), the removal of As (III) by pristine BC was negligibly contributed by the oxidized As (V) remaining in solutions, with the relative contribution <15.0%. For the BM composites, relative contribution of adsorbed As (III, V) dominated over that of oxidation to mobile As (V) remaining in solution, and exhibited the decreasing trend with increasing C₀. These findings demonstrated BM as a promising candidate in remediating As (III, V)-polluted water, and provide mechanistic insights into the role of oxidation and adsorption in As (III, V) removal.